Energy, Environmental, and Catalysis Applications
- Jiuda Wen
Jiuda Wen
Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, State Key Laboratory of Photovoltaic Materials and Cells, Nankai University, Tianjin 300350, P. R. China
Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Tianjin 300350, P. R. China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China
Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, P. R. China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
More by Jiuda Wen
- Youpeng Wang
Youpeng Wang
Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, State Key Laboratory of Photovoltaic Materials and Cells, Nankai University, Tianjin 300350, P. R. China
Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Tianjin 300350, P. R. China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China
Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, P. R. China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
More by Youpeng Wang
- Pengfei Liu
Pengfei Liu
Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, State Key Laboratory of Photovoltaic Materials and Cells, Nankai University, Tianjin 300350, P. R. China
Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Tianjin 300350, P. R. China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China
Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, P. R. China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
More by Pengfei Liu
- Zetong Sunli
Zetong Sunli
Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, State Key Laboratory of Photovoltaic Materials and Cells, Nankai University, Tianjin 300350, P. R. China
Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Tianjin 300350, P. R. China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China
Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, P. R. China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
More by Zetong Sunli
- Yuan Luo
Yuan Luo
Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, State Key Laboratory of Photovoltaic Materials and Cells, Nankai University, Tianjin 300350, P. R. China
Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Tianjin 300350, P. R. China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China
Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, P. R. China
See AlsoAURORA - An Automatic Robotic Platform for Materials DiscoveryTuning of MoS2 Photoluminescence in Heterostructures with CrSBrUnravelling Protein–Fungal Hyphae Interactions at the NanoscaleCoercive Field Control in Epitaxial Ferroelectric Hf0.5Zr0.5O2 Thin Films by Nanostructure EngineeringCollaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
More by Yuan Luo
- Xuejiao Wang
Xuejiao Wang
Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, State Key Laboratory of Photovoltaic Materials and Cells, Nankai University, Tianjin 300350, P. R. China
Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Tianjin 300350, P. R. China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China
Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, P. R. China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
More by Xuejiao Wang
- You Gao
You Gao
Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, State Key Laboratory of Photovoltaic Materials and Cells, Nankai University, Tianjin 300350, P. R. China
Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Tianjin 300350, P. R. China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China
Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, P. R. China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
More by You Gao
- Ying Zhao
Ying Zhao
Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, State Key Laboratory of Photovoltaic Materials and Cells, Nankai University, Tianjin 300350, P. R. China
Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Tianjin 300350, P. R. China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China
Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, P. R. China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
More by Ying Zhao
- Biao Shi*
Biao Shi
Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, State Key Laboratory of Photovoltaic Materials and Cells, Nankai University, Tianjin 300350, P. R. China
Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Tianjin 300350, P. R. China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China
Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, P. R. China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
*Email: [emailprotected]
More by Biao Shi
- Xiaodan Zhang*
Xiaodan Zhang
Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, State Key Laboratory of Photovoltaic Materials and Cells, Nankai University, Tianjin 300350, P. R. China
Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Tianjin 300350, P. R. China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China
Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, P. R. China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
*Email: [emailprotected]
More by Xiaodan Zhang
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ACS Applied Materials & Interfaces
Cite this: ACS Appl. Mater. Interfaces 2025, XXXX, XXX, XXX-XXX
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https://pubs.acs.org/doi/10.1021/acsami.5c03024
Published April 26, 2025
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The [4-(3,6-dimethyl-9H-carbazol-9-yl)butyl]phosphonic acid (Me-4PACz) self-assembled monolayer (SAM) deposited by solution processing has been widely used as an excellent hole-transporting material in high-performance inverted perovskite solar cells (PSCs). While vacuum-based evaporation of Me-4PACz offers significant potential for large-scale PSC fabrication, its application is hindered by the poor wettability of the evaporated SAM, which adversely affects the device performance. In this work, an evaporated cuprous thiocyanate (CuSCN) film was employed to modify the evaporated Me-4PACz, which can improve the wettability, leading to enhanced coverage and uniformity of the perovskite film. In addition, the incorporation of CuSCN established an energy level gradient at the SAM–perovskite interface, facilitating efficient hole transport. Moreover, the CuSCN layer contributed to interface passivation, effectively reducing interface recombination losses. As a result, an efficiency of 21.62% for single-junction wide-bandgap PSCs (1.68 eV) was achieved. Additionally, the films fabricated by evaporation show good uniformity on a large-area substrate, laying a foundation for large-area PSCs.
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- Evaporation
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ACS Applied Materials & Interfaces
Cite this: ACS Appl. Mater. Interfaces 2025, XXXX, XXX, XXX-XXX
Click to copy citationCitation copied!
Published April 26, 2025
Publication History
Received
Accepted
Revised
Published
online
© 2025 American Chemical Society
Request reuse permissions
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